30.) Harman, W. H. "Stabilizing sulfur: Synthesis of a terminal Fe^III=S complex," Chem 2023, 9, 2368–2370. [link]

Invited Preview for https://doi.org/10.1016/j.chempr.2023.05.007

29.) Raviprolu, V. T; Farias, P.; Harman, W. H.; Lavallo, V. "When the Ferrocene Analogy Breaks Down: Metallocene Transmetallation Chemistry," Angew. Chem. Int. Ed. 2023, 62, e202308359. [link]

28.) Xu, S.; Essex, L. A.; Nguyen, J. Q.; Farias, P.; Ziller, J. W.; Harman, W. H.; Evans, W. J. "Cooperative dinitrogen capture by a diboraanthracene/samarocene pair," Dalton Trans. 2021, 50, 15000–15002. [link]

27.) Huynh, W.; Taylor, J. W.; Harman, W. H.; Conley, M. P. "Solid-state ¹¹B NMR studies of coinage metal complexes containing a phosphine substituted diboraanthracene ligand," Dalton Trans. 2021, 50, 14855–14863. [link] 

26.) Taylor, J. W.; Harman, W. H. “H₂ evolution from H₂O via O–H oxidative addition across a 9,10-diboraanthracene,” Chem. Commun. 2020, 56, 13804–13807. [link]

25.) Ngai, C.; Sanchez-Marsetti, C.M.; Harman, W. H.; Hooley, R.J. "Supramolecular Catalysis of the oxa‐Pictet–Spengler Reaction with an Endohedrally Functionalized Self‐Assembled Cage Complex,” Angew. Chem. Int. Ed. 2020, 59, 23505–23509. [link]

24.) McSkimming, A.; Taylor, J. W.; Harman, W. H. “Assembly and Redox-Rich Hydride Chemistry of an Asymmetric Mo₂S₂ Platform,” Molecules 2020, 25, 3090. [link]
Invited contribution to “Solar Fuels: A Themed Issue in Honor of Professor Harry B. Gray on the Occasion of His 85th Birthday."

23.) Essex, L. A.; McSkimming A.; Thompson, N. B.; A.; Kelty, M. L.; Hill, E. A.; Harman, W. H. "η²-Arene Binding at High-Spin Fe(I) Enabled by a Sterically Accomodating Tris(pyrazolyl)hydroborate Ligand,” Organometallics 2020, 39, 2545–2552. [link]

22.) Taylor, J. W.; Harman, W. H. "C=O Scission and Reductive Coupling of Organic Carbonyls by a Redox-Active Diboraanthracene,” Chem. Commun. 2020, 56, 4480–4483. [link]

21.) Taylor, J. W.; McSkimming, A.; Essex, L. A.; Harman, W. H. "CO₂ Reduction with Protons and Electrons at a Boron-Based Reaction Center,” Chem. Sci. 2019, 10, 9084–9090. DOI: 10.1039/C9SC02792K [link]

20.) Essex, L. A.; Taylor, J. W.; Harman, W. H. "Nickel Complexes of Phosphine-Appended Benzannulated Boron Heterocycles,” Tetrahedron 2019, 75, 2255–2260. DOI: 10.1016/j.tet.2019.02.047 [link]
Special Issue on Organoboranes and Frustrated Lewis Pairs

19.) Taylor, J. W.; McSkimming, A.; Moret, M.–E.; Harman, W. H. "Copper and Silver Complexes of a Redox-Active Diphosphine-Diboraanthracene Ligand,” Inorg. Chem. 2018, 57, 15406–15413. DOI: 10.1021/acs.inorgchem.8b02710 [link]

18.) Miller, T. F.; Holloway, L. R.; Nye, P. P.; Lyon, Y.; Beran, G. J. O.; Harman, W. H.; Julian, R. R.; Hooley, R. J. "Small Structural Variations Have Large Effects on the Assembly Properties and Spin State of Room Temperature High Spin Fe(II) Iminopyridine Cages,” Inorg. Chem. 2018, 57, 13386–13396. DOI: 10.1021/acs.inorgchem.8b01973 [link]
 

17.) Huang, Z.; Xu, Z.; Mahboub, M.; Li, X.; Taylor, J. W.; Harman, W. H.; Lian, T.; Tang, M. “PbS/CdS core/shell QDs suppress charge transfer and enhance triplet transfer,” Angew. Chem. Int. Ed. 2017, 56, 16583–16587. DOI: 10.1002/ange.201710224. [link]

16.) Taylor, J. W.; McSkimming, A.; Guzman, C. F.; Harman, W. H. “NHC-Stabilized Boranthrene as a Metal-Free Platform for the Activation of Small Molecules,” J. Am. Chem. Soc. 2017, 139, 11032–11035. DOI: 10.1021/jacs.7b06772. [link]
JACS Spotlight: Small-Molecule Activation without the Need for Transition Metals

15.) Taylor, J. W.; McSkimming, A.; Moret, M.-E.; Harman, W. H. “A Molecular Boroauride: A Donor-Acceptor Complex of Anionic Gold,” Angew. Chem. Int. Ed. 2017, 56, 10413–10417., DOI: 10.1002/anie.201703235. [link]
Featured on the inside back cover

14.) McSkimming, A.; Harman, W. H. “A Terminal N₂ Complex of High-Spin Iron(I) in a Weak, Trigonal Ligand Field.” J. Am. Chem. Soc. 2015, 137, 8940–8943. [link]

13.) Harman, W. H.; Lin, T.-P.; Peters, J. C. “A d¹⁰ Ni–(H₂) Adduct as an Intermediate in H–H Oxidative Addition across a Ni–B Bond.” Angew. Chem. Int. Ed. 2014, 53, 1081–1086.[link]
 

12.) MacMillan, S. N.; Harman, W. H.; Peters, J. C. “Facile Si–H bond activation and hydrosilylation catalysis mediated by a nickel–borane complex,” Chem. Sci. 2014, 5, 590–597. [link]
 

11.) Harman, W. H.; Lichterman, M. F.; Piro, N. A.; Chang, C. J. “Well-Defined Vanadium Organoazide Complexes and Their Conversion to Terminal Vanadium Imides: Structural Snapshots and Evidence for a Nitrene Capture Mechanism,” Inorg. Chem. 2012, 51, 10037–10042. [link]
 

10.) Harman, W. H.; Peters, J. C. “Reversible H₂ Addition Across a Nickel–Borane Unit as a Promising Strategy for Catalysis,” J. Am. Chem. Soc. 2012, 134, 5080–5082. [link]
 

9.) Bigi, J. P.; Harman, W. H.; Lassalle-Kaiser, B.; Robles, D. M.; Stich, T. A.; Yano, J.; Britt, R. D.; Chang, C. J. “A High-Spin Iron(IV)-Oxo Complex Supported by a Nonheme Pyrrolide Platform,” J. Am. Chem. Soc. 2012, 134, 1536–1542. [link]
 

8.) Piro, N. A.; Lichterman, M. F.; Harman, W. H.; Chang, C. J. “A Structurally Characterized Nitrous Oxide Complex of Vanadium,” J. Am. Chem. Soc. 2011, 133, 2108–2111. [link]
 

7.) Harman, W. H.; Harris, T. D.; Freedman, D. E.; Fong, H.; Chang, A.; Rinehart, J. D.; Ozarowski, A.; Sougrati, M. T.; Grandjean, F.; Long, G. J.; Long, J. R.; Chang, C. J. “Slow Magnetic Relaxation in a Family of Trigonal Pyramidal Iron(II) Pyrrolide Complexes,” J. Am. Chem. Soc. 2010, 132, 18115–18126. [link]
 

6.) Bigi, J. P; Hanna, T. E.; Harman, W. H.; Chang, A.; Chang, C. J. “Electrocatalytic reduction of protons to hydrogen by a water-compatible cobalt polypyridyl platform,” Chem. Commun. 2010, 46, 958–960. [link]
 

5.) Freedman, D. E.; Harman, W. H.; Harris, T. D.; Long, G. J.; Chang, C. J.; Long, J. R. “Slow Magnetic Relaxation in a High-Spin Iron(II) Complex,” J. Am. Chem. Soc. 2010, 132, 1224–1225. [link]
 

4.) Harman, W. H.; Chang, C. J. “N₂O Activation and Oxidation Reactivity from a Nonheme Iron Pyrrole Platform,” J. Am. Chem. Soc. 2007, 129, 15128–15129. [link]
 

3.) Kazhdan, D.; Chomitz, W. A.; Harman, W. H.; Hoette, T. M.; Park, C.-H. “(Bipyridyl-κ²N,N’)bis(η⁵-pentamethylcyclopentadienyl)(trifluoromethanesulfonato- κO)cerium(III). Acta Crystallogr., Sect. E: Struct. Rep. Online 2007, E63, m1656. [link]
 

2.) Delafuente, D. A.; Kosturko, G. W.; Graham, P. M.; Harman, W. H.; Myers, W. H.; Surendranath, Y.; Klet, R. C.; Welch, K. D.; Trindle, C. O.; Sabat, M.; Harman, W. D. “Isomerization Dynamics and Control of the η²/N Equilibrium for Pyridine Complexes,” J. Am. Chem. Soc. 2007, 129, 406–416. [link]
 

1.) Surendranath, Y.; Welch, K. D.; Nash, B. W.; Harman, W. H.; Myers, W. H.; Harman, W. D. “Tungsten-Promoted Dearomatization of Heterocycles: Uncovering the Latent 2-Azadiene Character of Pyrimidines,” Organometallics 2006, 25, 5852–5853. [link]